Aminosilane-Functionalized Zeolite Y in Pebax Mixed Matrix Hollow Fiber Membranes for CO 2 /CH 4 Separation.

Due to their interfacial defects between inorganic fillers and polymer matrices, research into mixed matrix membranes (MMMs) is challenging. In the application of CO 2 separation, these defects can potentially jeopardize the performance of membranes. In this study, aminosilane functionalization is employed to improve the nano-sized zeolite Y (ZeY) particle dispersion and adhesion in polyether block amide (Pebax). The performance of CO 2 /CH 4 separation of Pebax mixed matrix composite hollow fiber membranes, incorporated with ZeY and aminosilane-modified zeolite Y (Mo-ZeY), is investigated. The addition of the zeolite filler at a small loading at 5 wt.% has a positive impact on both gas permeability and separation factor. Due to the CO 2 -facilitated transport effect, the performance of MMMs is further improved by the amino-functional groups modified on the ZeY. When 5 wt.% of Mo-ZeY is incorporated, the gas permeability and CO 2 /CH 4 separation factor of the Pebax membrane are enhanced by over 100% and 35%, respectively.