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Solid Parahydrogen Thickness Revisited.

Mario E Fajardo
Published in: Applied spectroscopy (2019)
We report updated infrared (IR) absorption measurements on vapor-deposited cryogenic parahydrogen (pH2) solids that indicate a ≈10% systematic error in our previous approach for determining a pH2 solid's thickness (S. Tam and M.E. Fajardo. Appl. Spectrosc. 2001. 55(12): 1634-1644). We provide corrected values for the integrated absorption intensities of the Q1(0)+S0(0) and S1(0)+S0(0) bands calculated over the 4495-4520 cm-1 and 4825-4855 cm-1 regions, respectively. New polarized IR absorption spectroscopy data demonstrate the insensitivity to polarization effects of the peak intensity of the QR(0) phonon sideband near 4228 cm-1. This feature provides an even quicker way for determining the thickness of a pH2 solid than via the integrated absorptions.
Keyphrases
  • optical coherence tomography
  • machine learning
  • deep learning
  • high intensity
  • mass spectrometry
  • solid state