Direct Observation of Magnetic Domain and Magnetization Reversal on Prussian Blue-Based Magnetic Films.

Knowledge of the magnetic domain is indispensable for understanding the magnetostatic properties of magnets. However, to date, the magnetic domain has not yet been reported in the field of molecule-based magnets. Herein, we study the magnetic domains of molecule-based magnets. Two magnetic films of iron/chromium hexacyanidochromate Fe x Cr 1- x [Cr(CN) 6 ] 2/3 ·5H 2 O ( x = 0; Film 1 and x = 0.2; Film 2 ) were prepared for investigation. The temperature evolution of surface magnetization was measured using magnetic force microscopy. Film 1 showed a magnetic domain below Curie temperature ( T C ) and its positive-magnetic polarization increased monotonously with decreasing temperature, while Film 2 showed positive magnetic polarization below T C and switches from positive to negative magnetization through a demagnetization state at 146 K. This study originally reports the temperature variation of the magnetization state at the magnetization reversal. The magnetic domains appeared as a maze pattern with an approximate domain size of one-to-several micrometers. This work shows that research on molecule-based magnets can be expanded from magnetochemistry to the magnetostatic engineering of bulk magnets, molecule-based magnetostatic engineering.