Heavier N-heterocyclic half-sandwich tetrylenes.
Inga-Alexandra BischoffBernd MorgensternAndré SchäferPublished in: Chemical communications (Cambridge, England) (2022)
ansa -Half-sandwich complexes of the group 14 elements germanium, tin and lead are reported, which represent a new class of Lewis amphiphilic tetrylenes and bridge the gap between classical N-heterocyclic systems and group 14 metallocenes. These compounds can form complexes both with carbenes and transition metal fragments.
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