X-ray CT observation and characterization of water transformation in heavy objects.

Nondestructive observations and characterization of low-density materials composed of low-Z elements, such as water or its related substances, are essential for materials and life sciences. However, visualizing these compounds and their phase changes is still challenging. In this study, an approach to X-ray imaging of water-related substances in heavy objects without the use of contrast agents is proposed. The implementation of the approach is based upon X-ray phase shift, in which the optimal photon energy is simulated for high-contrast X-ray imaging. Proof of concept is provided by observations of resins, water, and clathrate hydrates such as CO2 hydrate and tetrahydrofuran (THF) hydrate in an aluminum container by diffraction-enhanced X-ray imaging with synchrotron X-rays of 35 keV. These results suggest that the proposed approach is a unique method for visualizing the transformation of these clathrate hydrates and is also applicable to in situ observations of other objects composed of multiphase materials with small density differences.