Reversible Dissociation of a Dialumene*.
Rosalyn L FalconerKeelan M ByrneGary S NicholTobias KrämerMichael J CowleyPublished in: Angewandte Chemie (International ed. in English) (2021)
Dialumenes are neutral AlI compounds with Al=Al multiple bonds. We report the isolation of an amidophosphine-supported dialumene. Our X-ray crystallographic, spectroscopic, and computational DFT analyses reveal a long and extreme trans-bent Al=Al bond with a low dissociation energy and bond order. In solution, the dialumene can dissociate into monomeric AlI species. Reactivity studies reveal two modes of reaction: as dialumene or as aluminyl monomers.