Regioselective 1,4-/1,3-Difunctionalization of 1,3-Enynes with Selenosulfonates in Water.

Hong-He DengShi-Yin TianJia-Hui HanXin-Yu LiuWei-Dong RaoShu-Su ShenDaopeng ShengZhao-Ying YangShun-Yi Wang

Published in: The Journal of organic chemistry (2024)

1,4-/1,3-Regioselective bifunctionalization of 1,3-enynes with selenosulfonates in water under catalyst-free conditions for the construction of sulfonyl allene and 1,3-disulfonyl-conjugated dienes respectively have been developed. The reactions feature mild reaction conditions in aqueous solution and remarkable regioselectivity controlled by substrates.

Keyphrases

aqueous solution
machine learning
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ionic liquid
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room temperature
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reduced graphene oxide
carbon dioxide
neural network