The template effect of a SiF 6 2- guest drives the formation of a heteroleptic Fe(II) coordination helicate.

Nuria CapóLeoní A BarriosJoan CardonaJordi Ribas-Ariño Simon J Teat Olivier Roubeau Guillem Aromí

Published in: Chemical communications (Cambridge, England) (2022)

The anion SiF 6 2- exerts a strong template effect, driving the exclusive assembly of two different bispyridylpyrazolyl ligands into a triple stranded Fe(II) dinuclear heteroleptic helicate, engendering a new class within the large family of coordination helicates.

Keyphrases

molecularly imprinted
metal organic framework
binding protein
ionic liquid
aqueous solution
nucleic acid