Login / Signup

Homogeneous Deposition of Zinc on N-Doped Carbon Fibers Interconnected with Sn Nanoparticles for Advanced Aqueous Zinc Batteries.

Bixia WangJiayi HaoHui XuMinxi SunChun WuWei QinXing-Qiao WuQiliang Wei
Published in: ACS applied materials & interfaces (2024)
Currently, inhomogeneous distribution of Zn 2+ on the surface of the Zn anode is still the essential reason for dendrite formation and unsatisfactory stability of zinc ion batteries. Given the merits of strong interaction between Sn and Zn, as well as a low nucleation barrier during Zn deposition, the combination of metallic Sn with carbon material is expected to improve the deposition of zinc ions and inhibit the growth of zinc dendrites by guiding the homogeneous plating/stripping of zinc on the electrode surface. In this article, zincophilic Sn nanoparticles with low nucleation barriers and strong interaction with Zn 2+ were embedded into 3D N-doped carbon nanofibers using a simple electrostatic spinning technique. Accordingly, when serving as an artificial coating layer for the zinc metal anode, an ultrastable Sn@NCNFs@Zn||Sn@NCNFs@Zn symmetric cell can be achieved for over 3500 h with a low nucleation overpotential of 29.1 mV. Significantly, the full cell device assembled with the as-prepared anode and MnO 2 cathode exhibits desirable electrochemical behaviors. Moreover, this simple method could be extended to other metal-carbon composites, and to ensure ease in scaling up as required. Such significant approach can provide an effective strategy for the design of high-performance zinc anodes.
Keyphrases
  • ion batteries
  • oxide nanoparticles
  • heavy metals
  • reduced graphene oxide
  • quantum dots
  • single cell
  • risk assessment
  • mass spectrometry
  • bone marrow
  • mesenchymal stem cells
  • highly efficient
  • carbon nanotubes