Stereodynamical Control of Cold Collisions of Polyatomic Molecules with Atoms.

Scattering between atomic and/or molecular species can be controlled by manipulating the orientation or alignment of the collision partners. Such stereodynamics is particularly pronounced at cold (∼1 K) collision temperatures because of the presence of resonances. Comparing to the extensively studied atomic and diatomic species, polyatomic molecules with strong steric anisotropy could provide a more sophisticated platform for studying such stereodynamics. Here, we provide the quantum mechanical framework for understanding state-to-state stereodynamics in rotationally inelastic scattering of polyatomic molecules with atoms and apply it to cold collision of oriented H 2 O with He on a highly accurate potential energy surface. It is shown that strong stereodynamical control can be achieved near 1 K via shape resonances. Furthermore, quantum interference in scattering of a coherently prepared initial state of the H 2 O species is explored, which is shown to be significant.