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Five shades of green: substituent influence on the (spectro-) electrochemical properties of diferrocenyl(phenyl)methylium dyes.

Larissa A CasperViktoria EbelMichael LinseisRainer F Winter
Published in: Dalton transactions (Cambridge, England : 2003) (2021)
Five new, intensely green diferrocenylphenylmethylium complexes 1+-5+ with electron donating (EDG: 4-MeO, 4-Me, 4-Br) or withdrawing (EWG: 3,5-CF3, 4-nC6F13) substituents were synthesized and fully characterized. The substituent influence on their electrochemical and spectroscopic properties was investigated by cyclic voltammetry, UV/Vis/NIR and T-dependent EPR spectroscopy of the cationic as well as the oxidized (12+-52+) and reduced (1˙-5˙) species. The reduced forms equilibrate with their corresponding dimers (65-83%) with a clear substituent influence as expressed by their Hammett parameters in an ordering 4+ > 5+ > 3+ > 2+ > 1+. The structures of all five precursor carbinols 1-OH-5-OH and those of three of the diferrocenylphenylmethylium cations (1+, 4+-5+) were established by X-ray crystallography.
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