Presence and Spatial Distribution of Polynuclear Aromatic Hydrocarbons (PAHs) in Groundwater of Merida City, Yucatan, Mexico.

The karstic aquifer of Yucatan features a high permeability, therefore, all contaminants placed in the soil surface, can reach it through infiltration along with the rain water. The purpose of the present study is to determine the spatial distribution of the aromatic hydrocarbons in the underground water of Merida City. Fifty wells inside the city were sampled. The sampling took place during the dry season, from October 2007 to March 2008. Liquid-liquid Hydrocarbon extraction was performed using hexane and purification was made by previously packed chromatography columns. Regarding the occurrence of polynuclear aromatic hydrocarbon (PAHs) traces, 28 water samples (56%) contained residues of these compounds. The following PAHs presented the highest concentrations: benzo(a)anthracene y benzo(k)fluoranthene 13.26 and 7.88 µg L-1 respectively. Only three of the sampled wells showed levels above those allowed by EPA and WHO norms. The origin of these compounds is mainly pyrogenic.