Ni-Doped In 2 O 3 Nanoparticles and Their Composite with rGO for Efficient Degradation of Organic Pollutants in Wastewater under Visible Light Irradiation.
Amir HabibMuhammad Shahzeb KhanMuhammad ZubairIftikhar Ul HasanPublished in: International journal of molecular sciences (2023)
The efficient degradation of organic effluent is always desirable when using advanced photocatalysts with enhanced activity under visible light. Nickel-doped indium oxide (Ni-In 2 O 3 ) is synthesized via a hydrothermal route as well as its composites with reduced graphene oxide (rGO). Facile synthesis and composite formation methods lead to a well-defined morphology of fabricated nanocomposite at low temperatures. The bandgap energy of indium oxide lies in the range of 3.00-4.30 eV. Its high light absorption capacity, high stability, and non-toxicity make it a choice as a photocatalyst that is active under visible light. The transition metal Ni-doping changes the indium oxide's chemical, optical, and physicochemical properties. The Ni-In 2 O 3 and rGO composites improved the charge transport and reduced the charge recombination. The phase analysis of the developed photocatalysts was performed using X-ray diffraction (XRD), and the morphological and structural properties were observed using advanced microscopic techniques (SEM and TEM), while UV-vis and FTIR spectroscopic techniques were used to confirm the structure and optical and chemical properties. The electrochemical properties of the photocatalysts were investigated using cyclic voltammetry (CV), linear sweep voltammetry (LSV), and electrochemical impedance spectroscopy (EIS), and the charge-transfer properties of the obtained photocatalysts and the mechanism of the photocatalytic degradation mechanism of methylene blue, a common dye used in the dyeing industry, were determined.
Keyphrases
- visible light
- reduced graphene oxide
- transition metal
- gold nanoparticles
- high resolution
- metal organic framework
- oxide nanoparticles
- anaerobic digestion
- dna damage
- oxidative stress
- dna repair
- mass spectrometry
- molecular docking
- high speed
- radiation induced
- risk assessment
- molecularly imprinted
- decision making
- magnetic resonance imaging
- liquid chromatography
- magnetic resonance