Synthesis of the A/D/E-ring Core Compounds of Maoecrystal V.
Hiroki AsaoYasuharu ShimasakiAyaka SasakiShunki KatayamaKousuke IdaMasaaki KotakeEriko SatoYuki SatoTaiki IshimotoMinoru IzumiChristopher J VavrickaKuwahara ShigefumiHiromasa KiyotaPublished in: Bioscience, biotechnology, and biochemistry (2024)
Synthesis of the A/D/E-ring core compounds of maoecrystal V was achieved. The key Diels-Alder reactions between tricyclic α-methylene lactones and Kitahara-Danishefsky dienes afforded the spirocyclic core compounds in a regioselective and stereoselective manner.
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