Effect of Extremely Short-Sized MWCNT as Additive Material in High Surface Area Activated Carbon and Its Enhanced Electrical LIC Performance.

Extremely short-sized multi-wall carbon nanotube (CNT) and high surface area activated carbon were used to increase the electrical performance of lithium-ion capacitors (LIC). After electrodes were synthesized using extremely short-sized CNTs and high specific surface area activated carbon, their electrochemical characteristics were evaluated by XRD, SEM, TEM, cyclic voltammetry, EIS, BET, adoption isotherm, t-plot, and pore size distribution. In the process of electrode preparation using extremely short-sized CNTs and high specific surface area activated carbon, CNTs certainly caused a space-filling effect between these two materials, which had a significant effect on the evaluation of electrical characteristics. These relationships were demonstrated by the results of adsorption-desorption isotherm, pore size distribution, t-plot, and BJH plot. Particularly, in the electrochemical cyclic test, as the content of CNT increased, the current density significantly increased with the formation of a near-perfect rectangular shape. This tendency also exhibited excellent characteristics in a t-I plot, Tafel plot, and LSV plot, which clearly affected the electrochemical oxidation-reduction reaction due to the densification of filling density and space structure by adding extremely short-sized CNTs to the active material. In addition, YP80_CNT3 formed a specific resistance value in the range of 7.2 to 6.2 Ω/cm 2 , showing significantly reduced values compared to other samples. This research presented herein offers a promising route for the rational design of MWCNT and stable electrochemical reaction with LIC working mechanism.