Investigation of Dimethylammonium Solubility in MAPbBr3 Hybrid Perovskite: Synthesis, Crystal Structure, and Optical Properties.

The possible existence of mixed methylammonium (MA)/dimethylammonium (DMA) lead bromide hybrid perovskites of general formula MA1- xDMA xPbBr3 (0 ≤ x ≤ 1) was investigated. A combined X-ray diffraction and solid-state nuclear magnetic resonance approach indicates that DMA can be incorporated up to about x = 0.30 while retaining the cubic lattice of MAPbBr3. By increasing the DMA content ( x), the absorption shows a progressive blue shift and the band gap moves from about 2.17 eV ( x = 0) to about 2.23 ( x = 0.30) with a concomitant slightly faster recombination in the mixed cation powders.