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Disilenyl Silylene Reactivity of a Cyclotrisilene.

Hui ZhaoKinga LeszczyńskaLukas KlemmerVolker HuchMichael ZimmerDavid Scheschkewitz
Published in: Angewandte Chemie (International ed. in English) (2018)
The highly reactive silicon congeners of cyclopropene, cyclotrisilenes (c-Si3 R4 ), typically undergo either π-addition to the Si=Si double bond or σ-insertion into the Si-Si single bond. In contrast, treatment of c-Si3 Tip4 (Tip=2,4,6-i Pr3 C6 H2 ) with styrene and benzil results in ring opening of the three-membered ring to formally yield the [1+2]- and [1+4] cycloaddition product of the isomeric disilenyl silylene to the C=C bond and the 1,2-diketone π system, respectively. At elevated temperature, styrene is released from the [1+2]-addition product leading to the thermodynamically favored housane species after [2+2] cycloaddition of styrene and c-Si3 Tip4 .
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