Instability Issues and Stabilization Strategies of Lead Halide Perovskites for Photo(electro)catalytic Solar Fuel Production.

Photo(electro)catalysis is a promising route to utilizing solar energy to produce valuable chemical fuels. In recent years, lead halide perovskites (LHPs) as a class of high-performance semiconductor materials have been extensively used in photo(electro)catalytic solar fuel production because of their excellent photophysical properties. However, instability issues make it arduous for LHPs to achieve their full potential in photo(electro)catalysis. This Perspective discusses the instability issues and summarizes the stabilization strategies employed for prolonging the stability or durability of LHPs in photo(electro)catalytic solar fuel production. The strategies for particulate photocatalytic systems (including composition engineering, surface passivation, core-shell structures construction, and solvent selection) and for thin-film PEC systems (including physical protective coating, A site cation additive, and surface/interface passivation) are introduced. Finally, some challenges and opportunities regarding the development of stable and efficient LHPs for photo(electro)catalysis are proposed.