Recent developments in visible light induced polymerization towards its application to nanopores.

Visible light induced polymerizations are a strongly emerging field in recent years. Besides the often mild reaction conditions, visible light offers advantages of spatial and temporal control over chain growth, which makes visible light ideal for functionalization of surfaces and more specifically of nanoscale pores. Current challenges in nanopore functionalization include, in particular, local and highly controlled polymer functionalizations. Using spatially limited light sources such as lasers or near field modes for light-induced polymer functionalization is envisioned to allow local functionalization of nanopores and thereby improve nanoporous material performance. These light sources are usually providing visible light while classical photopolymerizations are mostly based on UV-irradiation. In this review, we highlight developments in visible light induced polymerizations and especially in visible light induced controlled polymerizations as well as their potential for nanopore functionalization. Existing examples of visible light induced polymerizations in nanopores are emphasized.