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C(sp 3 )-H Ritter amination by excitation of in situ generated iodine(III)-BF 3 complexes.

Rok NarobeKathiravan MurugesanChristoph HaagTobias Emanuel SchirmerBurkhard König
Published in: Chemical communications (Cambridge, England) (2022)
Visible light excitation of iodine(III)-BF 3 complex enables the formation of carbocations from C(sp 3 )-H bonds. The complexes are generated catalytically from iodoarene, carboxylate ligand, the oxidizing agent Selectfluor, and the Lewis acid BF 3 . This modular catalytic system allows the formation of synthetically valuable amine derivatives without a metal- or photocatalyst.
Keyphrases
  • visible light
  • dual energy
  • energy transfer
  • computed tomography
  • magnetic resonance imaging
  • magnetic resonance
  • highly efficient
  • crystal structure
  • quantum dots