Ruthenium dioxide nanoparticles as a high-capacity transducer in solid-contact polymer membrane-based pH-selective electrodes.

A new approach is presented for the design of ion selective electrodes. Ruthenium dioxide nanoparticles were incorporated into solid-contact electrodes, and their properties were studied for the case of pH-selective electrodes. The use of the RuO2 is shown to significantly improve the potentiometric response, while no redox response is observed. The use of RuO2 results in a Nernstian slope (59 mV/decade) towards hydrogen ions over a wide linear range (pH 2 to 12). The results obtained by chronopotentiometry reveal small resistance, and the capacitance is as high as 1.12 mF. This results in a good stability of the response and in a low potential drift (0.89 μV∙s-1). The electrodes exhibit properties nearly as excellent as those of a glass electrode, but they are much smaller, less fragile, and easy to use. Graphical abstractSchematic representation of the construction of the new kind of electrodes along with calibration and chronopotentiometric plots compared to non-modified GCD/H+-ISM and modified GCD/RuO2/H+-ISM electrodes, respectively. The use of ruthenium dioxide results in a wide analytical pH range (2-12) and in high electrical capacitance (1.12 mF).