Superconducting dome associated with the suppression and re-emergence of charge density wave states upon sulfur substitution in CuIr 2 Te 4 chalcogenides.

We report the path from the charge density wave (CDW)-bearing superconductor CuIr 2 Te 4 to the metal insulator transition (MIT)-bearing compound CuIr 2 S 4 by chemical alloying with the gradual substitution of S for Te. The evolution of structural and physical properties of the CuIr 2 Te 4- x S x (0 ⩽ x ⩽ 4) polycrystalline system is systemically examined. The x-ray diffraction (XRD) results imply CuIr 2 Te 4- x S x (0 ⩽ x ⩽ 0.5) crystallizes in a NiAs defected trigonal structure, whereas it adapts to the cubic spinel structure for 3.6 ⩽ x ⩽ 4 and it is a mixed phase in the doping range of 0.5 < x < 3.6. Unexpectedly, the resistivity and magnetization measurements reveal that small-concentration S substitution for Te can suppress the CDW transition, but it reappears around x = 0.2, and the CDW transition temperature enhances clearly as x augments for 0.2 ⩽ x ⩽ 0.5. Besides, the superconducting critical temperature ( T c ) first increases with S doping content and then decreases after reaching a maximum T c = 2.82 K for CuIr 2 Te 3.85 S 0.15 . MIT order has been observed in the spinel region (3.6 ⩽ x ⩽ 4) associated with T MI increasing with x increasing. Finally, the rich electronic phase diagram of temperature versus x for this CuIr 2 Te 4- x S x system is assembled, where the superconducting dome is associated with the suppression and re-emergence of CDW as well as MIT states at the end upon sulfur substitution in the CuIr 2 Te 4- x S x chalcogenides.