Kinetics of Micellization and Liquid-Liquid Phase Separation in Dilute Block Copolymer Solutions.

A lattice theory for block copolymer solutions near the boundary between the micellization and liquid-liquid phase separation regions proposes a new kinetic process of micellization where small concentrated-phase droplets are first formed and then transformed into micelles in the early stage of micellization. Moreover, the thermodynamically stable concentrated phase formed from metastable micelles by a unique ripening process in the late stage of phase separation, where the growing concentrated-phase droplet size is proportional to the square root of the time.