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Facile assembly of 1,5-diazocan-2-ones via cyclization of tethered sulfonamides to cyclopropenes.

Jonathon P MathenyPavel M YamanushkinPeter A PetilloMichael Rubin
Published in: RSC advances (2020)
The sulfonamide moiety was evaluated as an activating and stabilizing functional group in the metal-templated strain release-driven intramolecular nucleophilic addition of amines to cyclopropenes to generate 1,5-diazocan-2-ones.
Keyphrases
  • signaling pathway
  • quantum dots
  • reduced graphene oxide
  • highly efficient
  • energy transfer
  • solid phase extraction
  • metal organic framework
  • high resolution
  • tandem mass spectrometry