A Fe(III)/NaBH4-Promoted Free-Radical Hydroheteroarylation of Alkenes.

Bingyu LiangQinglong WangZhong-Quan Liu

Published in: Organic letters (2017)

A free-radical-mediated intermolecular hydroheteroarylation of simple alkenes was developed. Through simply mixing heteroarenes, alkenes, Fe(III), and NaBH4 at 0 °C together, a wide range of alkylated heteroarenes could be afforded in moderate to excellent yields within 1 h.

Keyphrases

metal organic framework
high intensity
visible light
energy transfer
quantum dots