The Application of Metal-Organic Frameworks and Their Derivatives for Supercapacitors.

Supercapacitors (SCs), one of the most popular types of energy-storage devices, present lots of advantages, such as large power density and fast charge/discharge capability. Being the promising SCs electrode materials, metal-organic frameworks (MOFs) and their derivatives have gained ever-increasing attention due to their large specific surface area, controllable porous structure and rich diversity. Herein, the recent development of MOFs-based materials and their application in SCs as the electrode are reviewed and summarized. The preparation method, the morphology of the materials and the electrical performance of various MOFs and their derivatives (such as carbon, metal oxide/hydroxide and metal sulfide) are briefly discussed. Most of recent works concentrate on Ni-, Co- and Mn-MOFs and their composites/derivatives. Conclusions and our outlook for the researches are also given, which would be a valuable guideline for the rational design of MOFs materials for SCs in the near future.