A square planar silylene nickel four-membered ring.
Sebastian KaufmannRalf KöppePeter W RoeskyPublished in: Dalton transactions (Cambridge, England : 2003) (2021)
Herein the new nickel silylene [PhC(NtBu)2SiNi(C5Me5)]2, which features a square planar central ring motif consisting of two silicon and two nickel atoms is presented. The title compound was obtained by an insertion of the Ni(0) precursor [Ni(cod)2] (cod = 1,5-cyclooctadiene) in the Si-C bond of the silylene [PhC(NtBu)2Si(C5Me5)]. Analytic characterisation including mass spectrometry as well as IR and Raman spectroscopies was combined with quantum chemical calculations to get an insight on the bonding situation within the four-membered Si-Ni-ring.
Keyphrases
- metal organic framework
- mass spectrometry
- room temperature
- transition metal
- molecular dynamics
- reduced graphene oxide
- oxide nanoparticles
- carbon nanotubes
- liquid chromatography
- high resolution
- density functional theory
- molecular dynamics simulations
- high performance liquid chromatography
- ms ms
- quantum dots
- energy transfer