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The H2 S Dimer is Hydrogen-Bonded: Direct Confirmation from Microwave Spectroscopy.

Arijit DasPankaj K MandalFrank J LovasChris MedcraftNicholas R WalkerElangannan Arunan
Published in: Angewandte Chemie (International ed. in English) (2018)
Ice and solid H2 S look as different as pears and oranges, leading Pauling to conclude that H2 O has hydrogen bonds and H2 S has van der Waals interactions. Now it is shown that the H2 S dimer, like the H2 O dimer, is indeed hydrogen-bonded.
Keyphrases
  • visible light
  • high resolution
  • single molecule
  • mass spectrometry
  • radiofrequency ablation
  • transition metal