Design of Bowl-Shaped N-Hydroxyimide Derivatives as New Organoradical Catalysts for Site-Selective C(sp3 )-H Bond Functionalization Reactions.

Published in: Angewandte Chemie (International ed. in English) (2020)

A series of new bowl-shaped N-hydroxyimide derivatives has been designed and used as selective organoradical catalysts. A number of these bowl-shaped N-hydroxyimide derivatives exhibit excellent site-selectivity in the amination of benzylic C(sp3 )-H bonds in aromatic hydrocarbon substrates.

Keyphrases

transition metal
highly efficient
amino acid
structural basis
solid state