A pyridine-capped quaterthiophene as an alternative to PEDOT:PSS, processable from organic solvents and without acidity, for more stable electronic devices.

Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) is a material that has become ubiquitous in the field of organic electronics. It is most commonly used as a hole transport layer (HTL) in optoelectronic devices and can be purchased commercially in various formulations with different properties. Whilst it is a most convenient material to work with, there are stability issues associated with PEDOT:PSS that are detrimental to device stability and these are due to the acidic nature of the PSS component. In this paper, we present a molecular, non-acidic alternative to PEDOT:PSS. The parent structure is composed of a quater(3,4-ethylenedioxythiophene) unit capped either side of the short chain with two pyridine units. This compound, termed (BEDOTPy) 2 , can be prepared chemically and electrochemically to give doped materials with a choice of counteranions. Further functionalisation via quaternisation at the nitrogen atoms allows for modification of solubility and film-forming properties. The conductivity of the doped samples can reach up to 3.75 S cm -1 . The materials are non-acidic and are therefore attractive alternatives to PEDOT:PSS for device applications. We demonstrate an OLED device using the compound (BEDOTPy-EtOH-I) 2 PF 6 as an HTL, and compare the device performance to one made with PEDOT:PSS. Due to the non-acidic nature of the molecular material, the corresponding OLED device does not show a drop in luminance over time, whereas a loss of performance is observed for the device containing PEDOT:PSS over a short period. These results are presented to introduce the parent compound (BEDOTPy) 2 as an attractive alternative to PEDOT:PSS, which can be easily modified chemically to provide a plethora of potential compounds with tunable properties.