Predicting the impact sensitivity of a polymorphic high explosive: the curious case of FOX-7.
Adam A L MichalchukSvemir RudićColin R PulhamCarole A MorrisonPublished in: Chemical communications (Cambridge, England) (2021)
The impact sensitivity (IS) of FOX-7 polymorphs is predicted by phonon up-pumping to decrease as layers of FOX-7 molecules flatten. Experimental validation proved anomalous owing to a phase transition during testing, raising questions regarding impact sensitivity measurement and highlighting the need for models to predict IS of polymorphic energetic materials.
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