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Spectroscopic and reactive characterization of mixed-metal Fe-Cr trimer nodes in metal-organic framework MIL-100.

Jacklyn N HallPraveen Bollini
Published in: Chemical communications (Cambridge, England) (2023)
Metal-organic framework MIL-100 is synthesized featuring heterometallic Fe and Cr M 3 O nodes where mixing of the metals within the nodes is evidenced using a combination of in situ IR spectroscopy, NO titrations, and CO oxidation kinetics. Reactivity data indicate distinctive properties of the bimetallic nodes.
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