Organophosphonate-Bridged Polyoxometalate-Based Dysprosium(III) Single-Molecule Magnet.

Yu HuoRong WanPengtao MaJunliang LiuYancong ChenDandan LiJingyang NiuJingping WangMing-Liang Tong

Published in: Inorganic chemistry (2018)

A novel dysprosium(III)-containing polytungstoarsenate, [{(AsW9O33)3Dy2(H2O)4W4O9(H2O)}2(NH2(CH2PO3)2)]33-, comprising two identical subunits bridged by an organophosphonate ligand shows single-molecule-magnet (SMM) behavior. Magnetic studies reveal that this complex exhibits a butterfly-shaped hysteresis loop up to 8 K, and a thermally activated energy barrier of 101(5) K reached a breakthrough among all polyoxometalate-supported SMMs.

Keyphrases

single molecule
room temperature
living cells
atomic force microscopy
metal organic framework
transcription factor
single cell
molecularly imprinted
case control
gene expression
dna methylation
mass spectrometry
high speed