Light-Driven C-C Coupling for Targeted Synthesis of CH 3 COOH with Nearly 100 % Selectivity from CO 2 .

Jinyu DingPeijin DuJuncheng ZhuQing HuDongpo HeYang WuWenxiu LiuShan ZhuWensheng YanJun HuJunfa ZhuQingxia ChenXingchen JiaoYi Xie

Published in: Angewandte Chemie (International ed. in English) (2024)

The CO 2 photoreduction towards CH 3 COOH with nearly 100 % selectivity is realized over a catalyst with charge asymmetric metal pair sites, wherein the metal charge asymmetric active sites induced by doping engineering can boost the C-C coupling of double COOH* intermediates.

Keyphrases

room temperature
ionic liquid
solar cells
cancer therapy
drug delivery
transition metal
carbon dioxide