Strong circularly polarized luminescence via intramolecular excited-state symmetry-breaking charge separation.

Maria João Álvaro-MartinsChloé BilliauxPascale GodardReiko Oda Guillaume Raffy Dario M Bassani

Published in: Chemical communications (Cambridge, England) (2023)

Trans -1,2-di(1-pyrenylamino)cycloxexane was found to display circularly polarized excimer emission ( g lum = 0.016) both in polar and non-polar solvents that is assigned to charge separation symmetry breaking on the basis of its large transition state dipole moment (12.1 D).

Keyphrases

ionic liquid
liquid chromatography
energy transfer
solar cells
quantum dots
mass spectrometry
biofilm formation
pseudomonas aeruginosa