Geminal bimetallic coordination of a carbone to main-group and transition metals.
Akachukwu D ObiChun-Lin DengAndrew J AlexisDiane A DickieRobert J GilliardPublished in: Chemical communications (Cambridge, England) (2024)
The non-bonding carbone lone pair in geometrically-constrained antimony and bismuth carbodiphosphorane complexes readily complexed AuCl to afford rare examples of geminal bimetallic carbone coordination featuring a main-group metal.