Tomography of Feshbach resonance states.
Baruch MargulisKarl P HornDaniel M ReichMeenu UpadhyayNitzan KahnArthur ChristianenAd van der AvoirdGerrit C GroenenboomChristiane P KochMarkus MeuwlyEdvardas NareviciusPublished in: Science (New York, N.Y.) (2023)
Feshbach resonances are fundamental to interparticle interactions and become particularly important in cold collisions with atoms, ions, and molecules. In this work, we present the detection of Feshbach resonances in a benchmark system for strongly interacting and highly anisotropic collisions: molecular hydrogen ions colliding with noble gas atoms. The collisions are launched by cold Penning ionization, which exclusively populates Feshbach resonances that span both short- and long-range parts of the interaction potential. We resolved all final molecular channels in a tomographic manner using ion-electron coincidence detection. We demonstrate the nonstatistical nature of the final-state distribution. By performing quantum scattering calculations on ab initio potential energy surfaces, we show that the isolation of the Feshbach resonance pathways reveals their distinctive fingerprints in the collision outcome.
Keyphrases
- energy transfer
- quantum dots
- loop mediated isothermal amplification
- molecular dynamics
- label free
- real time pcr
- density functional theory
- single molecule
- human health
- molecular dynamics simulations
- biofilm formation
- water soluble
- sensitive detection
- climate change
- escherichia coli
- carbon dioxide
- liquid chromatography