Systematic Study of the Behavior of Different Metal and Metal-Containing Particles under the Microwave Irradiation and Transformation of Nanoscale and Microscale Morphology.

In recent years, the application of microwave (MW) irradiation has played an increasingly important role in the synthesis and development of high performance nanoscale catalytic systems. However, the interaction of microwave irradiation with solid catalytic materials and nanosized structures remains a poorly studied topic. In this paper we carried out a systematic study of changes in morphology under the influence of microwave irradiation on nanoscale particles of various metals and composite particles, including oxides, carbides, and neat metal systems. All systems were studied in the native solid form without a solvent added. Intensive absorption of microwave radiation was observed for many samples, which in turn resulted in strong heating of the samples and changes in their chemical structure and morphology. A comparison of two very popular catalytic materials-metal particles (M) and supported metal on carbon (M/C) systems-revealed a principal difference in their behavior under microwave irradiation. The presence of carbon support influences the heating mechanism; the interaction of substances with the support during the heating is largely determined by heat transfer from the carbon. Etching of the carbon surface, involving the formation of trenches and pits on the surface of the carbon support, were observed for various types of the investigated nanoparticles.