Investigating Electronic Communications in meso-meso Ethene-Bridged Unsymmetrical Diporphyrins.
Anna ZieleniewskaDirk Michael GuldiPublished in: Chemistry (Weinheim an der Bergstrasse, Germany) (2019)
At the focal point of this work is the photophysical characterization of three meso-meso ethene-bridged diporphyrins featuring a diverse metallation pattern. Detailed investigations by means of cyclic voltammetry, absorption, fluorescence, and femto-/nanosecond transient absorption spectroscopy revealed the impact of open-shell nickel(II) on the electronic communication in ethene-bridged heterobimetallic diporphyrins.