Efficient Tuning of the Opto-Electronic Properties of Sol-Gel-Synthesized Al-Doped Titania Nanoparticles for Perovskite Solar Cells and Functional Textiles.

The efficient electron transport layer (ETL) plays a critical role in the performance of perovskites solar cells (PSCs). Ideally, an unobstructed network with smooth channels for electron flow is required, which is lacking in the pristine TiO 2 -based ETL. As a potential solution, here we tuned the structure of TiO 2 via optimized heteroatom doping of Al. Different concentrations (1, 2, and 3 wt%) of Al were doped in TiO 2 and were successfully applied as an ETL in PSC using spin coating. A significant difference in the structural, opto-electronic, chemical, and electrical characteristics was observed in Al-doped TiO 2 structures. The opto-electronic properties revealed that Al doping shifted the absorption spectra toward the visible range. Pure titania possesses a bandgap of 3.38 eV; however, after 1, 2, and 3% Al doping, the bandgap was linearly reduced to 3.29, 3.25, and 3.18 eV, respectively. In addition, higher light transmission was observed for Al-doped TiO 2 , which was due to the scattering effects of the interconnected porous morphology of doped-TiO 2 . Al-doped titania shows higher thermal stability and a 28% lower weight loss and can be operated at higher temperatures compared to undoped titania (weight loss 30%) due to the formation of stable states after Al doping. In addition, Al-doped TiO 2 showed significantly high conductivity, which provides smooth paths for electron transport. Thanks to the effective tuning of band structure and morphology of Al-doped TiO 2 , a significant improvement in current densities, fill factor, and efficiency was observed in PSCs. The combined effect of better Jsc and FF renders higher efficiencies in Al-doped TiO 2 , as 1, 2, and 3% Al-doped TiO 2 showed 12.5, 14.1, and 13.6% efficiency, respectively. Compared to undoped TiO 2 with an efficiency of 10.3%, the optimized 2% Al doping increased the efficiency up to 14.1%. In addition, Al-doped TiO 2 also showed improvements in antibacterial effects, required for photoactive textiles.