Silver halide complexes of a borane/bis(phosphine) ligand.

Yihan CaoWei-Chun ShihNattamai BhuvaneshOleg V Ozerov

Published in: Dalton transactions (Cambridge, England : 2003) (2019)

Silver halide complexes of a borane/bis(phosphine) ligand have been prepared and characterized. With AgF, the borane abstracts fluoride, resulting in a zwitterionic complex. With AgCl, AgBr, and AgI, the halide stays coordinated to Ag, with little to no Ag-B interaction.

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