Towards a quantitative bond valence description of coordination spheres - the concepts of valence entropy and valence diversity coordination numbers.

Two novel definitions of chemical coordination numbers - valence entropy coordination number nVECN and valence diversity coordination number nVDCN - are proposed. Their originality stems from the fact that they are the first definitions based solely on bond valences. The expressions for them are derived from their definitions and their properties are studied. The unexpected close relationship of nVECN to Shannon entropy and nVDCN to diversity are revealed and the names of the new coordination numbers are taken therefrom. Finally, as an example, a study of arsenic(III) lone electron pair stereoactivity with respect to AsIII coordination number is carried out to demonstrate the usefulness and advantages of the new definitions as well as to compare them with the existing ones.