Transition-Metal-Free Borylation of Allylic and Propargylic Alcohols.
Núria MirallesRauful AlamKálmán J SzabóElena FernándezPublished in: Angewandte Chemie (International ed. in English) (2016)
The base-catalyzed allylic borylation of tertiary allylic alcohols allows the synthesis of 1,1-disubstituted allyl boronates, in moderate to high yield. The unexpected tandem performance of the Lewis acid-base adduct, [Hbase](+) [MeO-B2 pin2 ](-) favored the formation of 1,2,3-triborylated species from the tertiary allylic alcohols and 1-propargylic cyclohexanol at 90 °C.
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