Three triphenylamine derivatives containing ferrocenyl groups (JW6, JW7 and JW8) were synthesized by facile syntheses. Their HOMO levels match the valence band energy of CH 3 NH 3 PbI 3 . The introduction of ferrocenyl was aimed to obtain hole transporting materials with high mobility for perovskite solar cells. JW7 shows higher hole mobility (4.2 × 10 -4 cm 2 V -1 s -1 ) than JW6 (1.3 × 10 -4 cm 2 V -1 s -1 ) and JW8 (1.5 × 10 -4 cm 2 V -1 s -1 ). Their film-forming properties are affected by their molecule structures. The methoxyl and N , N -dimethyl terminal substituents of JW7 and JW8 are beneficial for having better solubility than JW6. The regular mesoporous TiO 2 -based perovskite solar cells (n-i-p) and the inverted planar heterojunction perovskite solar cells (p-i-n) fabricated using JW7 show the highest power conversion efficiency of 9.36% and 11.43% under 100 mW cm -2 AM1.5G solar illumination. For p-i-n cells, the standard HTM PEDOT-based cell reaches an efficiency of 12.86% under the same conditions.