Synthesis of the Proposed Structure of Mohangic Acid C.
Keisuke TakahashiShunya KudoKiharu KawamuraTaichi KusakabeShoko KikkawaIsao AzumayaKeisuke KatoPublished in: Organic letters (2022)
The proposed structure of mohangic acid C ( 3 ) was stereoselectively synthesized via a catalytic asymmetric aldol reaction to install a p -aminoacetophenone moiety, Marshall propargylation furnishing two stereocenters, and Cu-mediated Stille-type coupling to construct the whole framework of 3 .
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