Arraying Octahedral {Cr2Dy4} Units into 3D Single-Molecule-Magnet-Like Inorganic Compounds with Sulfate Bridges.

Two novel 3D pure inorganic compounds based on [Cr2Dy4(μ4-O)2(μ3-OH)4]10+ cluster units and sulfate anions are presented. Both complexes exhibit single-molecule-magnet (SMM)-like behavior. Permutation of the magnetic moment direction among SMM-like cluster units has a significant effect on the performance of molecular nanomagnets, and directional consistency shows obvious advantages.