Functional Catechol-Metal Polymers via Interfacial Polymerization for Applications in Water Purification.

Phenols and polyphenols have been used as a scaffold for generating multidimensional molecular architectures via complexation with metal ions. Here, we report the synthesis and characterization of metallopolymer films from three catechol derivatives having different alkyl/aryl substituents via complexation with iron and copper ions at the organic-water interface. Such interfacial polymerization is instantaneous, one step to generate functional materials, and gives good control over the organization of repeating units along the film. The films were transferred to different substrates such as filter paper, cotton, or polyester fabrics. The films are superhydrophobic with a contact angle >160° which can be tuned by regulating the orientation of nonpolar groups at the interface during polymerization. In addition, the fabricated cloth membrane showed excellent oil/water separation efficiency of more than 99% even after 50 cycles. The polymers also showed good dye extraction capacity from aqueous solutions with fast kinetics data. Such metallopolymer networks can serve as a versatile material for applications in catalysis, protective coatings, drug delivery, water filtration membranes, and liquid separations.