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Synchronized fractionation and phase separation in binary colloids.

Lian Dan YaoHong Yu ChenYan ShiYing LiangTian-Hui Zhang
Published in: Soft matter (2020)
Fractionation is necessary for self-assembly in multicomponent mixtures. Here, reversible fractionation and crystallization are realized and studied in two-dimensional binary colloids which are supersaturated by enhancing the attraction between colloidal particles. As a deep and fast supersaturation results in gels with a uniform distribution of binary particles, a gradual quasistatic supersaturation process leads to a two-step crystallization in which small particles and large particles are fractionated as coexisting crystal and liquid phases respectively. Fractionation occurs as well in the quasistatic melting of gels. We show that the synchronized fractionation and phase separation arises from the competition between the size-dependent repulsion and the tunable attraction. The results in this study demonstrate a robust mechanism of fractionation via phase separation, and have important implication in understanding the reversible formation of membraneless organelles in living cells.
Keyphrases
  • ionic liquid
  • living cells
  • fluorescent probe
  • high resolution
  • small cell lung cancer
  • mass spectrometry
  • solid state