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Upside/Downside statistical mechanics of nonequilibrium Brownian motion. II. Heat transfer and energy partitioning of a free particle.

Galen T CravenRenai ChenAbraham Nitzan
Published in: The Journal of chemical physics (2018)
The energy partitioning during activation and relaxation events under steady-state conditions for a Brownian particle driven by multiple thermal reservoirs of different local temperatures is investigated. Specifically, we apply the formalism derived in Paper I [G. T. Craven and A. Nitzan, J. Chem. Phys. 148, 044101 (2018)] to examine the thermal transport properties of two sub-ensembles of Brownian processes, distinguished at any given time by the specification that all the trajectories in each group have, at that time, energy either above (upside) or below (downside) a preselected energy threshold. Dynamical properties describing energy accumulation and release during activation/relaxation events and relations for upside/downside energy partitioning between thermal reservoirs are derived. The implications for heat transport induced by upside and downside events are discussed.
Keyphrases
  • density functional theory
  • molecular dynamics
  • atomic force microscopy