Tetrahedral iron featuring an appended Lewis acid: distinct pathways for the reduction of hydroxylamine and hydrazine.

John J KiernickiEmily E NorwineMatthias ZellerNathaniel K Szymczak

Published in: Chemical communications (Cambridge, England) (2019)

We present the preparation of a nitrogen-based bidentate ligand featuring an appended boron Lewis acid as well as its tetrahedral Fe2+ and Zn2+ complexes. These complexes act as platforms for hydrazine and hydroxylamine capture and reduction chemistry.

Keyphrases

fluorescent probe
heavy metals
risk assessment
drug discovery
molecularly imprinted
high resolution
mass spectrometry
metal organic framework
simultaneous determination
amino acid